Environ. Sci. Technol., January 21, 2009
Atmospheric chemistry of sulfuryl fluoride: Reaction with OH radicals, Cl atoms and O3, atmospheric lifetime, IR spectrum, and global warming potential
M. P. Sulbaek Andersen*†, D. R. Blake†, F. S. Rowland†, M. D. Hurley‡ and T. J. Wallington*‡Department of Chemistry, 572 Rowland Hall, University of California, Irvine, Irvine, CA 92697-2025, and Systems Analytics and Environmental Sciences Department, Ford Motor Company, Mail Drop SRL-3083, Dearborn, MI 48121-2053
Abstract
Sulfuryl fluoride (SO2F2) is a radiatively active industrial chemical released into the atmosphere in significant (ktonne/year) quantities. The potential for SO2F2 to contribute to radiative forcing of climate change needs to be assessed. Long path length FTIR/smog chamber techniques were used to investigate the kinetics of the gas-phase reactions of Cl atoms, OH radicals, and O3 with SO2F2, in 700 Torr total pressure of air or N2 at 296 ± 1 K. Upper limits of k(Cl + SO2F2) < 9 × 10−19, k(OH + SO2F2) < 1.7 × 10−14 and k(O3 + SO2F2) < 5.5 × 10−24 cm3 molecule−1 s−1 were determined. Reaction with Cl atoms, OH radicals, or O3 does not provide an efficient removal mechanism for SO2F2. The infrared spectrum of SO2F2 is reported and a radiative efficiency of 0.196 W m−2 ppbv−1 was calculated. Historic production data estimates are presented which provide an upper limit for expected atmospheric concentrations. The radiative forcing of climate change associated with emissions of SO2F2 depends critically on the atmospheric lifetime of SO2F2. Further research is urgently needed to define the magnitude of potential nonatmospheric sinks.
* Address correspondence to either author. e-mail: mads@sulbaek.dk (M.P.S.A.); twalling@ford.com (T.J.W.).
, †University of California.
, ‡Ford Motor Company.
Link to abstract: http://pubs.acs.org/doi/abs/10.1021/es802439f
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